Product ID:NORKOOL CONCENTRATE SLH 224C
MSDS Date:06/06/1991
FSC:6850
NIIN:00F026674
MSDS Number: BQJTQ

UNION CARBIDE CHEM. & PLASTICS CO INC

39 OLD RIDGEBURY RD
DANBURY, CT 06817-0001
US

Emergency Phone: 203-794-6753

Cage: 0TAZ2

UNION CARBIDE CORPORATION

DANBURY, CT 06817-0001 US

Telephone: 1-800-568-4000 / 732-563-5522

Cage: 0TAZ2

ETHYLENE GLYCOL, GLYCOL

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 95%

ACGIH TLV: C 127 MG/CUM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 2-5%

POTASSIUM PHOSPHATE, DIBASIC *92-4*

CAS: 7758-11-4

Fraction By Weight: 1-3%

POTASSIUM HYDROXIDE

CAS: 1310-58-3

RTECS: TT2100000

Fraction By Weight: 1-2%

OSHA PEL 2 MG/CUM (CEILING)

ACGIH TLV: 2 MG/CUM (CEILING)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

DIETHYLENE ETHER (DIOXANE), (DIETHYLENE DIOXIDE),

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: 0.0077%

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

SODIUM NITRITE

CAS: 7632-00-0

RTECS: RA1225000

Fraction By Weight: 0.3%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1073.43 G/L

RTECS: 9999999VO

LD50 LC50 Mixture:ORAL LD50 (RAT): 500 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGESTION: ABDOMINAL
DISCOMFORT/NAUSEA/VOMITING/DIZZINESS/DROWSINESS/MALAISE/BLURRED
VISION/IRRITATION/LUMBAR PAIN/OLIGURIA/UREMIA/CNS EFFECT.
INHALATION: IRRITATION OF NOSE & THROAT/HEADACHE/NAUSEA/V
OMITING/DIZZINESS/IRREGULAR EYE MOVEMENT. SKIN: IRRITATION
W/DISCOMFORT. EYE: STINGING/BLINK/TEAR/CONJUNCTIVA REDNESS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:INGESTION: CARDIAC FAILURE/PULMONARY
EDEMA/KIDNEY DAMAGE/FATAL/DEVELOPMENT OF WEAKNESS OF FACIAL
MUSCLES/DIMINISHED HEARING/DIFFICULTY W/SWALLOWING DURING LAST
STAGES OF SEVERE POISONING. INHALATION: CNS INVOLVEMENT
PARTICULARLY DIZZINESS & NYSTAGMUS. SKIN: SENSITIZATION
W/DEVELOPMENT OF ALLERGIC CONTACT DERMATITIS.
Medical Cond Aggravated by Exposure:KIDNEY DISEASE

First Aid:INGESTION: IF CONSCIOUS, GIVE 2 GLASSES OF WATER & INDUCE
VOMITING. IF MODERATE VOLUMES OF ETHYLENE GLYCOL (FEW OUNCES), THEN
GIVE 3-4 OUNCES OF HARD LIQUOR SUCH AS WHISKEY. SKIN: FLUSH
W/WATER. INHAL ATION: REMOVE TO FRESH AIR. EYES: IMMEDIATELY FLUSH
W/WATER & CONTINUE WASHING FOR SEVERAL MINUTES. OBTAIN MEDICAL
ATTENTION IN ALL CASES.

Flash Point Method:PMCC
Flash Point:260F (126.7C)
Lower Limits:3.2%
Upper Limits:15.3%
Extinguishing Media:ALCOHOL-TYPE OR ALL PURPOSE-TYPE FOAMS FOR LARGE
FIRES. USE WATER SPRAY, CO2, OR DRY CHEMICAL FOR SMALL FIRES.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:DURING A FIRE, AMMONIA &
NITROGEN-CONTAINING COMPOUNDS MAY BE PRODUCED.

Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. SMALL
SPILLS SHOULD BE FLUSHED W/LARGE QUANTITIES OF WATER. LARGER SPILLS
SHOULD BE COLLECTED FOR DISPOSAL.

Handling and Storage Precautions:KEEP CONTAINER CLOSED. USE W/ADEQUATE
VENTILATION. FOR INDUSTRY USE ONLY.
Other Precautions:AVOID CONTACT W/EYES, SKIN, & CLOTHING. AVOID
PROLONGED/REPEATED BREATHING OF MIST/VAPOR. DON'T SWALLOW. ANY USE
OF PRODUCT IN ELEVATED-TEMPERATURE PROCESSES SHOULD BE THOROUGHLY
EVALUATED TO ESTABLIS H/MAINTAIN SAFE OPERATING CONDITIONS.

Respiratory Protection:IF PERSONNEL EXPOSURE EXCEEDS EXPOSURE LIMITS,
WEAR NIOSH/MSHA APPROVED RESPIRATOR W/ORGANIC VAPOR CARTRIDGE &
DUST/MIST PREFILTER.
Ventilation:GENERAL (MECHANICAL) ROOM/LOCAL EXHAUST: AT POINTS WHERE
VAPOR IS EXPECTED TO BE VENTED TO WORKPLACE.
Protective Gloves:NATURAL RUBBER/NITRILE/NEOPRENE/PVC
Eye Protection:MONOGOGGLES OR FACESHIELD
Other Protective Equipment:EYE BATH, SAFETY SHOWER
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE/LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NOTE TO PHYSICIAN: GIVE ETHANOL INTRAVENOUSLY, AS 5% SOLUTION IN SODIUM
BICARBONATE, AT RATE OF 10 ML ETHANOL/HR. HEMODIALYSIS MAY BE
REQUIRED. 4-METHYLPYRAZOLE, POTENT INHIBITOR OF ALCOHOL DEHYDROGEN
ASE, MAY BE USED. RESPIRATORY SUPPORT W/MECHANICAL
VENTILATION/POSITIVE END-EXPIRATORY PRESSURE MAY BE REQUIRED.

Boiling Pt:B.P. Text:363.19F
Melt/Freeze Pt:M.P/F.P Text:<-69C/-75F
Vapor Pres:0.014
Vapor Density:2.22
Spec Gravity:1.13164
Evaporation Rate & Reference:(BU AC = 1): 0
Solubility in Water:100%
Appearance and Odor:TRANSPARENT GREENISH-BLUE LIQUID, MILD ODOR.
Percent Volatiles by Volume:95/WT

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG BASES, STRONG OXIDIZING AGENTS & MATERIAL REACTIVE
W/HYDROXYL COMPOUNDS
Stability Condition to Avoid:FIRE, ELEVATED TEMPERATURES
Hazardous Decomposition Products:CO, CO2, AMMONIA, &
NITROGEN-CONTAINING COMPOUNDS

Waste Disposal Methods:INCINERATE IN FURNACE WHERE PERMITTED UNDER
APPROPRIATE FEDERAL, STATE, & LOCAL REGULATIONS. AT VERY LOW
CONCENTRATION IN WATER, ETHYLENE GLYCOL IS READILY BIODEGRADABLE IN
A BIOLOGICAL WASTEWATER TRE ATMENT PLANT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.